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(E)-4-Bromo-2-(2-methoxyphenyliminomethyl)phenol

✍ Scribed by Gül, Zarife Sibel ;Erşahin, Ferda ;Ağar, Erbil ;Işık, Şamil

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
464 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The molecule of the title compound, C~14~H~12~BrNO~2~, is almost planar and the dihedral angle between the planes of the two aromatic rings is 3.8 (2)°. The molecule exists in the crystal structure in the phenol–imine tautomeric form, with the H atom located on O rather than on N. This H atom is involved in a strong intramolecular hydrogen bond.

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## Abstract FTIR and FT Raman spectra of 2‐bromo‐4‐chloro phenol (BCP) and 2‐chloro‐4‐nitro phenol (CNP) were recorded in the region 4000–400 and 4000–50 cm^−1^, respectively. The molecular structure, geometry optimization, and vibrational wavenumbers were investigated. The spectra were interpreted