The mononuclear Schiff base compound C 16 H 19 NOSSn or [(CH 3 ) 3 Sn(SC 6 H 4 -4-N C(H)C 6 H 4 -OH-2)] features a slightly distorted C 3 S tetrahedral geometry for Sn. The mean planes of the two benzene rings make a dihedral angle of 41.8 (2) , indicating nonplanarity of the molecule.
4-Bromo-2-{[2-(2-hydroxybenzylideneamino)phenylimino]phenylmethyl}phenol
✍ Scribed by Yang, Fengke ;Wang, Yan ;Zhang, Zhantao
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 415 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 26 H 19 BrN 2 O 2 , all bond lengths and angles show normal values. Two hydroxy groups are involved in intramolecular O-HÁ Á ÁN hydrogen bonds, which influence the molecular conformation. In the crystal structure, weak intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules into zigzag chains along the [101] direction.
📜 SIMILAR VOLUMES
The molecule of the title compound, C~14~H~12~BrNO~2~, is almost planar and the dihedral angle between the planes of the two aromatic rings is 3.8 (2)°. The molecule exists in the crystal structure in the phenol–imine tautomeric form, with the H atom located on O rather than on N. This H atom is inv
The molecule of the title compound, C 14 H 12 BrNO 2 , crystallizes in a zwitterionic form, with a strong intramolecular N-HÁ Á ÁO hydrogen bond. The dihedral angle between the aromatic rings is 9.3 (3) . Intermolecular O-HÁ Á ÁO hydrogen bonds generate C(8) chains running parallel to the [100] dire