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Dérivés C-glycosyliques. XXIV. Glycosyl-4-thiazoles

✍ Scribed by Jean M. J. Tronchet; Hansjörg Eder

Book ID
102855509
Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
816 KB
Volume
58
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

4‐C‐glycosylthiazoles have been prepared by reacting thiourea or thioacetamide with a 6‐S‐benzyl‐6‐chloro‐1,2‐O‐isopropylidene‐3‐O‐methyl‐α‐D‐xylo‐6‐thiohexofuranos‐5‐ulose (7). The latter compound which constitutes an interesting synthetic intermediate in carbohydrate chemistry has been obtained by successive oxidation and chlorination of 6‐S‐benzyl‐1,2‐O‐isopropylidene‐3‐O‐methyl‐α‐D‐6‐thioglucofuranose.

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