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Dérivés C-glycosyliques. XV Vinylogues d'homo-C-glycosides. Communication préliminaire

✍ Scribed by Jean M. J. Tronchet; Marie-Thérèse Campanini; Josiane Denoyelle; Jean-Bernard Zumwald

Publisher
John Wiley and Sons
Year
1973
Tongue
German
Weight
190 KB
Volume
56
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

1,2‐O‐Isopropylidene‐3‐O‐methyl‐α‐D‐xylo‐pentodialdo‐1,4‐furanose and its 3‐O‐benzyl analog have been reacted with pyridinyl‐3‐methylenetriphenylphosphorane and benzimidazolyl‐2‐methylenetriphenylphosphorane. The unsaturated sugars so obtained are vinylogs of homo‐C‐glycosides whose conformation is easily determined. They constitute useful model compounds for pharmacologic studies.

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