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Dérivés diglycosyliques. Communication préliminaire

✍ Scribed by Jean M. J. Tronchet; Ford Habashi; Olivier R. Martin; Alain P. Bonenfant; Bruno Baehler; Jean-Bernard Zumwald

Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
231 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis

Diglycosyl Derivatives. Preliminary communication

Novel types of diglycosyl compounds, some of them bearing a resemblance to natural di‐ or tri‐saccharides are described: a diglycosyldiyne (1), a diglycosylthiophene (2), a diglycosylaziridine (3), a diglycosyldioxolane (4), as well as six C,N‐diglycosylnitrones, 9b–9f and 14. These C,N‐diglycosylnitrones, on treatment with an acetylenic Grignard reagent, led to the expected acetylenic diglycosyl‐hydroxylamine 11, whereas diglycosylisoxazolines (f. ex. 10) were obtained when these nitrones underwent 1,3‐dipolar cycloaddition to acetylenic compounds.

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