The potential curves of some excited electronic states of Liz leading to dissociation fragments up to Lif(ls)'+ Li\*(l#(3d) have been calculated with a frozen core method for nuclear separations between 2 and 20 bohr. Six curves are found to be binding, the first four 'Ez and two \*IT,, states: four
DOUBLY EXCITED STATES OF Li+BELOW THEN= 2 ANDN= 3 THRESHOLDS OF Li2+
β Scribed by KWONG T. CHUNG; C.D. LIN
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 937 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0092-640X
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β¦ Synopsis
Over 540 doubly excited Li / resonances below the Li 2/ N Γ 2 and N Γ 3 thresholds are studied with the complex-rotation method. The resonance energy, autoionization width, relativistic correction to the energy, and mass polarization are tabulated for each state. The doubly excited states are grouped into Rydberg series labeled by the quantum numbers K, T, and A to display the systematic regularity along the series. The calculated resonance energies are expected to be accurate to within a few meV.
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