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The First Solid-State Structure of a Lithiated Diazomethane with C–Li and N–Li Bonds: {[Me3SiC(Li)N2]2·3 THF}∞

✍ Scribed by Neil Feeder; Mark A. Hendy; Paul R. Raithby; Ronald Snaith; Andrew E. H. Wheatley

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 454 KB
Volume: 1998
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(199805)1998:5<861::aid-ejoc861>3.0.co;2-j

No coin nor oath required. For personal study only.

✦ Synopsis

Reaction of n-butyllithium with Me 3 SiCHN 2 in THF affords the first example of a lithiated diazomethane with C-Li and N-Li bonds.

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