Dicobaltoctacarbonyl, [Co 2 (CO) 8 ], has always been the metal complex of choice in the widely used Pauson ± Khand reaction for the formation of bicyclo[3.3.0]octenones by the cyclocarbonylation of an alkene and an alkyne (Scheme 1). [1] Alternative sources of zero valent cobalt, namely [(indenyl)C
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Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson–Khand Reaction
✍ Scribed by Marie E. Krafft; Llorente V. R. Boñaga
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 260 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0044-8249
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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Cyclopentane derivatives ## Cyclopentane derivatives Q 0030 The Dienyl Pauson-Khand Reaction. -The reaction of dienyne (I) with CO produces a mixture of the cycloadducts (III), (IV) and (V). The formation of (V) represents a new [4 + 2 + 1] cycloaddition reaction for the construction of seven-membe