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Aqueous-Phase, Thermal Pauson—Khand Reactions in the Presence of Surfactants.

✍ Scribed by Marie E. Krafft; James A. Wright; Llorente V. R. Bonaga

Publisher
John Wiley and Sons
Year
2003
Weight
80 KB
Volume
34
Category
Article
ISSN
0931-7597

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Dodecacarbonyltetracobalt Catalysis in t
Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson–Khand Reaction
✍ Marie E. Krafft; Llorente V. R. Boñaga 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB 👁 2 views

Dicobaltoctacarbonyl, [Co 2 (CO) 8 ], has always been the metal complex of choice in the widely used Pauson ± Khand reaction for the formation of bicyclo[3.3.0]octenones by the cyclocarbonylation of an alkene and an alkyne (Scheme 1). [1] Alternative sources of zero valent cobalt, namely [(indenyl)C