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ChemInform Abstract: Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson—Khand Reaction.

✍ Scribed by Marie E. Krafft; Llorente V. R. Bonaga

Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Dodecacarbonyltetracobalt Catalysis in t
Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson–Khand Reaction
✍ Marie E. Krafft; Llorente V. R. Boñaga 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB 👁 1 views

Dicobaltoctacarbonyl, [Co 2 (CO) 8 ], has always been the metal complex of choice in the widely used Pauson ± Khand reaction for the formation of bicyclo[3.3.0]octenones by the cyclocarbonylation of an alkene and an alkyne (Scheme 1). [1] Alternative sources of zero valent cobalt, namely [(indenyl)C