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Diverse Evolution of [{Ph 2 P(CH 2 ) n PPh 2 }Pt(μ-S) 2 Pt{Ph 2 P(CH 2 ) n PPh 2 }] ( n = 2, 3) Metalloligands in CH 2 Cl 2

✍ Scribed by Mas-Ballesté, Rubén; Capdevila, Mercè; Champkin, Paul A.; Clegg, William; Coxall, Robert A.; Lledós, Agustí; Mégret, Claire; González-Duarte, Pilar


Book ID
126821588
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
172 KB
Volume
41
Category
Article
ISSN
0020-1669

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The Evolution of [{Ph2P(CH2)nPPh2}Pt(μ-S
✍ Rubén Mas-Ballesté; Gabriel Aullón; Paul A. Champkin; William Clegg; Claire Mégr 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

## Abstract Given the nucleophilicity of the {Pt~2~S~2~} ring, the evolution of [Pt~2~(μ‐S)~2~(P∩P)~2~] (P∩P=1,2‐bis(diphenylphosphino)ethane (dppe), 1,3‐bis(diphenylphosphino)propane (dppp)) metalloligands in the presence of the simplest electrophilic species, the proton, has been studied. Combine