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Reversible Polymerization and Cis−Trans Isomerization Equilibria in [PdCl 2 {Ph 2 P(CH 2 CH 2 O) 4 CH 2 CH 2 PPh 2 - P , P ‘}] Metallacrown Ethers

✍ Scribed by Smith, Dale C.; Gray, Gary M.

Book ID
126042904
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
109 KB
Volume
37
Category
Article
ISSN
0020-1669

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Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac