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[cis,cis,trans-RuCl2(CO)2{Ph2P(CH2CH2O)nCH2CH2PPh2-P,P'}]m (n = 4, 5; m = 1, 2, ...) Metallacrown Ethers. X-ray Crystal Structures of cis,cis,trans-RuCl2(CO)2{Ph2P(CH2CH2O)4CH2CH2PPh2-P,P'}, a Complex Which Exhibits Rotational Isomers in the Solid State, and [cis,cis,trans-RuCl2(CO)2{.mu.-Ph2P(CH2CH2O)4CH2CH2PPh2-P,P'}]2, an Unusual Dimetallacrown Ether

✍ Scribed by Gray, Gary M.; Varshney, Ashima; Duffey, Christina H.

Book ID
127036603
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
859 KB
Volume
14
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES

Erratum to β€œAn NMR spectroscopic study o
Erratum to β€œAn NMR spectroscopic study of the binding of alkali metal cations and methanol by cis Mo(CO)4{Ph2P(CH2CH2O)nCH2CH2PPh2-P,Pβ€²} (n=4,5) metallacrown ethers. The X-ray crystal structures of cis-Mo (CO)4 {Ph2P(CH2CH2O)4CH2CH2PPh2-P,Pβ€²} Β· MeOH and cis-Mo (CO)4 {Ph2P(CH2CH2O)4CH2CH2PPh2-P,Pβ€²} Β· H2O” [Inorganica chimica acta 246 (1996) 229–240]
✍ Gary M. Gray; Frederick P. Fish; Christina H. Duffey πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 38 KB
Metallacrown ethers with trans-tetracarb
Metallacrown ethers with trans-tetracarbonylmolybdenum(0) centers. X-ray crystal structures of trans-Mo(CO)4{Ph2P(CH2CH2O)nCH2CH2PPh2-P,Pβ€²} (n=3, 5) and trans-Mo(CO)4{Ph2P(CH2CH2O)2-1-C6H4-2-(OCH2CH2)2PPh2-P,Pβ€²}
✍ Christina H Duffey; Charles H Lake; Gary M Gray πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 263 KB

Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac