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Raman spectra of ditertiary phosphines Ph2P-(CH2)n-PPh2 (n = 1–4) and coordination shifts in (CO)4Mo[Ph2P-(CH2)n-PPh2] (n = 1, 2)

✍ Scribed by V. Deckert; C. Engert; U. Posset; W. Kiefer


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
930 KB
Volume
7
Category
Article
ISSN
0924-2031

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Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac