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Distribution of radioactivity in recoil-labelled toluene-14C

✍ Scribed by R. Visser; C. R. Redvanly; F. L. J. Sixma; A. P. Wolf

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 189 KB
Volume: 80
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19610800508

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✦ Synopsis

Abstract

Toluene‐^14^C~1~ produced by the thermal neutron irradiation of a mixture of benzene and 2‐methylpyrazine is not specifically labelled in the methyl group, ruling out simple hydrogen replacement in benzene by the recoiling carbon‐14 for at least some fraction of the radioactive toluene produced. Using a recently published degradation scheme, the distribution of radioactivity in the ring relative to the methyl group has now also been determined.

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