Direct spectrophotometric determination of rare earths in organic extracts with chlorophosphonazo III
✍ Scribed by Jan Vilímec; Karel Jakubec
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 192 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0026-265X
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📜 SIMILAR VOLUMES
## AbStlYlCt A simple method has been developed to determine micromolar concentrations of Nd(III), Th(IV) and UWI) in brine. The method involves the extractive separation of these cations from brine matrix species by using ChIorophosphonaxo III as extractant with 1-butanol as solvent, and the spec
The syntheses and punficatlon of p-acetylchlorophosphonazo (CPApA) are descrrbed A method IS proposed for the spectrophotometrx determmatlon of total rare earths with CPApA m 0 2 M hydrochlonc acid medmm at theu lsosbestic point (667 nm) At this wavelength, the absorbances of equal amounts of rare e
recommended procedure, and the aqueous phase was analysed using the conventional thoron method. Similar experiments were carried out with IoO/, T.B.P.-kerosene, and with aluminium nitrate salting agent. Some typical results are shown in Table I. The effect of foreign elements on the determination w