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Spectrophotometric determination of total rare earths in minerals with the chromogenic reagent p-acetylchlorophosphonazo

✍ Scribed by Jiao-Mai Pai; Ru Yang; Chung-Gin Hsu


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
371 KB
Volume
257
Category
Article
ISSN
0003-2670

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✦ Synopsis


The syntheses and punficatlon of p-acetylchlorophosphonazo (CPApA) are descrrbed A method IS proposed for the spectrophotometrx determmatlon of total rare earths with CPApA m 0 2 M hydrochlonc acid medmm at theu lsosbestic point (667 nm) At this wavelength, the absorbances of equal amounts of rare earths are very close to each other Beer's law IS obeyed for O-12 pg of rare earths m 25 ml of solution The method has been satlsfactordy apphed to the determmation of total rare earths m mmerals ulth a prior organic extraction