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Direct Observation of Conformation-Dependent Pathways in the Excited-State Proton Transfer of 7-Hydroxyquinoline in Bulk Alcohols

โœ Scribed by Park, Sun-Young; Kim, Hyung-Bae; Yoo, Byung Kuk; Jang, Du-Jeon

Book ID
118251563
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
287 KB
Volume
116
Category
Article
ISSN
0022-3654

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Solvation and excited-state proton trans
Solvation and excited-state proton transfer of 7-azaindole in alcohols
โœ Y. Chen; F. Gai; J.W. Petrich ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 562 KB

Fluorescence lifetime measurements of purified 7-azaindole in methanol and butanol as a function of temperature are performed. The results indicate that in alcohols there exists a population of 'I-azaindole that is solvated in such a way that excitedstate tautomerixation is no longer a viable mode o