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Direct observation of excited state intramolecular proton transfer kinetics in 3-hydroxyflavone

✍ Scribed by Woolfe, G. J.; Thistlethwaite, P. J.

Book ID: 120255710
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 899 KB
Volume: 103
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00413a026

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The static and transient fluorescence spectroscopy of 3-hydroxyflavone, 3HF, has been investigated as a function of deuteration of the 3-hydroxy group and the solvent. Small H/D isotope effects are observed for at least two of the simple rate constants for the excited-state dynamics. The isotope eff