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Unusual Temperature Dependence of Excited State Proton Transfer Rates in Alcohols

✍ Scribed by Cohen, Boiko; Huppert, Dan


Book ID
125974262
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
65 KB
Volume
104
Category
Article
ISSN
1089-5639

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Fluorescence lifetime measurements of purified 7-azaindole in methanol and butanol as a function of temperature are performed. The results indicate that in alcohols there exists a population of 'I-azaindole that is solvated in such a way that excitedstate tautomerixation is no longer a viable mode o