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Excited-State Double Proton Transfer in 7-Azaindole Analogues: Observation of Molecular-Based Tuning Proton-Transfer Tautomerism

โœ Scribed by Chou, Pi-Tai; Wei, Ching-Yen; Wu, Go-Ray; Chen, Wen-Sin

Book ID
126783071
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
50 KB
Volume
121
Category
Article
ISSN
0002-7863

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Solvation and excited-state proton trans
Solvation and excited-state proton transfer of 7-azaindole in alcohols
โœ Y. Chen; F. Gai; J.W. Petrich ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 562 KB

Fluorescence lifetime measurements of purified 7-azaindole in methanol and butanol as a function of temperature are performed. The results indicate that in alcohols there exists a population of 'I-azaindole that is solvated in such a way that excitedstate tautomerixation is no longer a viable mode o