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Excited-State Double Proton Transfer in 3-Formyl-7-azaindole: Role of the n π * State in Proton-Transfer Dynamics

✍ Scribed by Chou, Pi-Tai; Wu, Guo-Ray; Wei, Ching-Yen; Shiao, Mei-Ying; Liu, Yun-I


Book ID
121235312
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
121 KB
Volume
104
Category
Article
ISSN
1089-5639

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Fluorescence lifetime measurements of purified 7-azaindole in methanol and butanol as a function of temperature are performed. The results indicate that in alcohols there exists a population of 'I-azaindole that is solvated in such a way that excitedstate tautomerixation is no longer a viable mode o