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7-Azaindole-Assisted Lactam-Lactim Tautomerization via Excited-State Double Proton Transfer

✍ Scribed by Chou, Pi-Tai; Wei, Ching-Yen; Chang, Chen-Pin; Chiu, Chieng-Hwa

Book ID
126140837
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
292 KB
Volume
117
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Solvent-mediated proton transfer. The ro
Solvent-mediated proton transfer. The roles of solvent structure and dynamics on the excited-state tautomerization of 7-azaindole/alcohol complexes
✍ Dale McMorrow; Thijs J. Aartsma πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 496 KB

The time profile of the 7-azaindole tautomer emission in alcohol solvents consists of a superposition of two components with a different rise time. These observations are interpreted m terms of competitive hydrogen bonding leading to a ground-state equilibrium between different conformations of solu