Direct Kinetic Studies of Reactions of 3-Pentoxy Radicals with NO and O 2
โ Scribed by Deng, Wei; Davis, Andrew J.; Zhang, Lei; Katz, David R.; Dibble, Theodore S.
- Book ID
- 126161771
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 67 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
The reactions of GeH 3 with 02, NO, and NO 2 were studied via time-resolved infrared diode laser absorption spectroscopy over the temperature range 232-468 K for 02 and NO, and 252-407 for NO 2. The measured rate constants (in cm 3 molecule -1 s -1) were kGert3+o2 = (10 -13"18+ยฐ"18) exp[(874 + 146)/
The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc