Dimeric epoxy fatty acid methyl esters: formation, chromatography and mass spectrometry

✍ Scribed by J. Gilbert; M.J. Shepherd; J.R. Startin; J. Eagles

• Publisher: Elsevier Science
• Year: 1981
• Tongue: English
• Weight: 324 KB
• Volume: 28
• Category: Article
• ISSN: 0009-3084
• DOI: 10.1016/0009-3084(81)90034-7

✦ Synopsis

The formation of dimers is reported from the thermal treatment of a series of epoxy fatty acid methyl esters. These compounds were isolated from the reaction mixture by steric exclusion chromatography and were subsequently characterised by their high resolution electron impact and ammonia chemical ionisation mass spectra. The spectra were consistent in each case with the presence of a mixture of four possible positional isomers each containing an ether bridge linking a pair of fatty acid methyl esters across the carbon chains, with a keto group on a carbon adjacent to the bridge on one of the esters.