In the crystal structure of the title compound, [ZnBr 2 (C 4 H 4 N 2 ) 2 ], each Zn atom is coordinated by two Br atoms and two pyridazine ligands within a distorted tetrahedron to form a discrete complex. metal-organic papers m1860 Bhosekar et al. [ZnBr 2 (C 4 H 4 N 2 ) 2 ]
Diiodobis(pyridazine-κN)zinc(II)
✍ Scribed by Bhosekar, Gaurav ;Jess, Inke ;Näther, Christian
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 174 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the crystal structure of the molecular title compound, [ZnI 2 (C 4 H 4 N 2 ) 2 ], the Zn atom is coordinated by two I atoms and two pyridazine ligands, resulting in a slightly distorted ZnN 2 I 2 tetrahedral geometry.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.041 wR factor = 0.113 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Zn(C 6 H 6 N 2 O) 2 (C 7 H 5 O 3 ) 2 ], crystallizes as mononuclear molecules with distorted trigonal±bipyramidal zinc coordination. One of the 4-hydroxybenzoate ions is coordinated to zinc as a bidentate ligand, while the other is monodentate. Intermolecular hydrogen bonds betw