In the crystal structure of the molecular title compound, [ZnI 2 (C 4 H 4 N 2 ) 2 ], the Zn atom is coordinated by two I atoms and two pyridazine ligands, resulting in a slightly distorted ZnN 2 I 2 tetrahedral geometry.
Dibromobis(pyridazine-κN)zinc(II)
✍ Scribed by Bhosekar, Gaurav ;Jess, Inke ;Näther, Christian
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 124 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the crystal structure of the title compound, [ZnBr 2 (C 4 H 4 N 2 ) 2 ], each Zn atom is coordinated by two Br atoms and two pyridazine ligands within a distorted tetrahedron to form a discrete complex.
metal-organic papers m1860 Bhosekar et al. [ZnBr 2 (C 4 H 4 N 2 ) 2 ]
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.041 wR factor = 0.113 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Zn(C 14 H 8 Br 2 N 2 O 3 )(C 5 H 5 N) 2 ], the Zn II ion is coordinated by one N and two O atoms from a Schiff base ligand and by the N atoms of two pyridine molecules to form a distorted trigonal-bipyramidal geometry.