Diaquabis(4-chlorobenzoato-κO)bis-(N,N′-diethylnicotinamide-κN)zinc(II)
✍ Scribed by Sarı, Musa ;Gökçe, Gültekin ;Gökçe, Songül ;Şahin, Ertan ;Necefoğlu, Hacali
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 622 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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metal-organic papers m466 H. Necefoglu et al. [Zn(C 7 H 4 NO 4 ) 2 (C 10 H 14 N 2 O) 2 (H 2 O) 2 ] Acta Cryst. (2001). E57, m465±m466
In the title compound, [Zn(C 7 H 4 ClO 2 ) 2 (C 7 H 8 N 2 O 2 ) 2 ], the Zn II ion is coordinated by two N atoms from two methyl N-(3pyridyl)carbamate ligands and four O atoms from two bidentate 2-chlorobenzoate anions in a pseudo-octahedral geometry. The Zn-O distances are in the range 2.0484 (16)-
The Zn atom of the title complex, [Zn(NCS)~2~(C~7~H~8~N~4~O)~2~(H~2~O)~2~] or [Zn(SCN)~2~(H-Pysc)~2~(H~2~O)~2~] [H-Pysc = __N__-aminocarbonyl-__N__′-(3-pyridylmethylene)hydrazine], derived from the condensation of pyridine-3-carbaldehyde and semicarbazone, is located at a crystallographic centre of