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Bis(2-chlorobenzoato-κ2O,O′)bis[methyl N-(3-pyridyl)carbamato-κN]zinc(II)

✍ Scribed by Maroszová, Jaroslava ;Findoráková, Lenka ;Györyvá, Katarína ;Moncol, Jan ;Melník, Milan

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 333 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807019836

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✦ Synopsis

In the title compound, [Zn(C 7 H 4 ClO 2 ) 2 (C 7 H 8 N 2 O 2 ) 2 ], the Zn II ion is coordinated by two N atoms from two methyl N-(3pyridyl)carbamate ligands and four O atoms from two bidentate 2-chlorobenzoate anions in a pseudo-octahedral geometry. The Zn-O distances are in the range 2.0484 (16)-2.380 (2) A ˚, and the Zn-N distance is 2.1012 (18) A ˚. The molecules are linked into a chain along the c axis by N-HÁ Á ÁO and C-HÁ Á ÁCl hydrogen bonds.

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