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Bis(2-chlorobenzoato-κO)bis(phenazone-κO)zinc(II) 0.612-hydrate

✍ Scribed by Maroszová, Jaroslava ;Findoráková, Lenka ;Györyvá, Katarína ;Koman, Marian ;Melník, Milan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
78 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Zn(C 7 H 4 ClO 2 ) 2 (C 11 H 12 N 2 O) 2 ].-0.612H 2 O, is a mononuclear zinc(II) compound. The Zn atom lies on a crystallographic twofold rotation axis. It is coordinated in a distorted tetrahedral arrangement by two O atoms of two phenazone molecules and one carboxylate O atom from each of two 2-chlorobenzoate anions. Intramolecular O-HÁ Á ÁO hydrogen bonds may be effective in the stabilization of the structure.

📜 SIMILAR VOLUMES

Bis(2-chlorobenzoato-κ2O,O′)bis[methyl N
Bis(2-chlorobenzoato-κ2O,O′)bis[methyl N-(3-pyridyl)carbamato-κN]zinc(II)
✍ Maroszová, Jaroslava ;Findoráková, Lenka ;Györyvá, Katarína ;Moncol, Jan ;Melník 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 333 KB

In the title compound, [Zn(C 7 H 4 ClO 2 ) 2 (C 7 H 8 N 2 O 2 ) 2 ], the Zn II ion is coordinated by two N atoms from two methyl N-(3pyridyl)carbamate ligands and four O atoms from two bidentate 2-chlorobenzoate anions in a pseudo-octahedral geometry. The Zn-O distances are in the range 2.0484 (16)-

Bis(2,2′-bipyridine-κ2N,N′)(oxalato-κ2O,
Bis(2,2′-bipyridine-κ2N,N′)(oxalato-κ2O,O′)zinc(II) penta­hydrate
✍ Šestan Jurić, Marijana ;Planinić, Pavica ;Giester, Gerald 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 464 KB

Bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )(oxalato-j 2 O,O 0 0 0 )zinc(II) pentahydrate Marijana S ˘estan Juric ´,a \* Pavica Planinic ´a and Gerald Giester b a Rudjer Bos ˇkovic ´Institute,