Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.054 wR factor = 0.125 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Diiodidobis(1,10-phenanthroline-κ2N,N′)cadmium(II)
✍ Scribed by Cao, Ming-Lei ;Fang, Xin ;Yu, Hai-Yang ;Wang, Jun-Dong
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 251 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Diiodidobis(1,10-phenanthroline-2 N,N')cadmium (II)
📜 SIMILAR VOLUMES
The crystal structure of the title compound, [Cd(C 12 H 8 N 2 ) 2 -(H 2 O) 2 ][NbOF 5 ], consists of Cd II complex cations and Nb V complex anions. The Cd II and Nb V atoms both have a distorted octahedral geometry. The Nb-F bond trans to the Nb O bond is significantly longer than the other four Nb-
In the title polymeric complex, [Cd(C 4 H 2 O 4 )(C 12 H 8 N 2 )-(H 2 O) 2 ] n , the Cd II ions are bridged by fumarate dianions to form zigzag complex chains.stacking is observed between the parallel phenanthroline ligands of neighboring complex chains. The Cd ion is located on a twofold axis and h