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cis-Dichloridobis(1,10-phenanthroline-κ2N,N′)­cadmium(II) hemihydrate

✍ Scribed by Li, Wei-Hua ;Liu, Fa-Qian ;Pang, Xue-Hui ;Hou, Bao-Rong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
133 KB
Volume
63
Category
Article
ISSN
1600-5368

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The crystal structure of the title compound, [Cd(C 12 H 8 N 2 ) 2 -(H 2 O) 2 ][NbOF 5 ], consists of Cd II complex cations and Nb V complex anions. The Cd II and Nb V atoms both have a distorted octahedral geometry. The Nb-F bond trans to the Nb O bond is significantly longer than the other four Nb-