Diaquabis(1,10-phenanthroline-κ2N,N′)cadmium(II) pentafluorooxoniobate(V)
✍ Scribed by Zhu, Gang ;Tang, Zongxun
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 311 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The crystal structure of the title compound, [Cd(C 12 H 8 N 2 ) 2 -(H 2 O) 2 ][NbOF 5 ], consists of Cd II complex cations and Nb V complex anions. The Cd II and Nb V atoms both have a distorted octahedral geometry. The Nb-F bond trans to the Nb O bond is significantly longer than the other four Nb-F bonds.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.054 wR factor = 0.125 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.
Diiodidobis(1,10-phenanthroline-2 N,N')cadmium (II)