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Dichloridobis(1,10-phenanthroline-κ2N,N′)tungsten(II)

✍ Scribed by Xu, Wei ;Lin, Jian-Li

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
129 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [WCl~2~(C~12~H~8~N~2~)~2~], the W atom has a distorted six-coordinate octahedral geometry. There are some π–π stacking interactions in the structure, which are responsible for the supramolecular assembly.

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A second polymorph of dichloridobis(1,10
A second polymorph of dichloridobis(1,10-phenanthroline-κ2N,N′)tungsten(II)
✍ Xu, Wei ;Lin, Jian-Li 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 131 KB

The title compound, [WCl 2 (C 12 H 8 N 2 ) 2 ], is a six-coordinate complex with a distorted octahedral geometry around the W atom. C-HÁ Á ÁCl hydrogen-bond interactions andstacking interactions are responsible for the supramolecular assembly.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.054 wR factor = 0.125 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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