Difluoro(η5-bis-1,3-trimethylsilylcyclopentadienyl) (η5-trimethylsilylcyclopentadienyl)titanium(IV)
✍ Scribed by Charles H. Winter; T. Suren Lewkebandara; Xuiqi Shui; Xiao -Xing Zhou
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 218 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1572-8854
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound, [Ti 2 ( 5 -C 5 H 5 ) 4 (N 3 ) 2 O], is a dinuclear oxobridged azido complex with two titanocene fragments connected through the oxygen bridge. The environment around each Ti atom can be considered as a distorted tetrahedron.
The central bridging O atom of the title homodinuclear titanocene complex, [Ti 2 (C 17 H 15 F 6 ) 2 Cl 4 O], lies on a crystallographic inversion center. The Ti IV ion has a distorted tetrahedral coordination geometry defined by two Cl atoms, a cyclopendienyl ring and the O atom.