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Bis-η5-cyclopentadienyl and Bis-η5-methylcyclopentadienylN,N-dialkyldithiocarbamato(chloro)titanium(IV) compounds

✍ Scribed by Narender K. Kaushik; Bharat Bhushan; Gurdeep R. Chhatwal

Publisher
Springer
Year
1978
Tongue
English
Weight
234 KB
Volume
3
Category
Article
ISSN
0340-4285

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The title compound, [Ti 2 ( 5 -C 5 H 5 ) 4 (N 3 ) 2 O], is a dinuclear oxobridged azido complex with two titanocene fragments connected through the oxygen bridge. The environment around each Ti atom can be considered as a distorted tetrahedron.

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In the crystal structure of the title vanadocene complex, [V( 5 -C 5 H 5 ) 2 (NCS) 2 ], the V atom has distorted tetrahedral coordination with two 5 -bonded cyclopentadienyl rings and two Nbonded thiocyanate ligands.