✦ LIBER ✦

Diels-Alder reactions of protoanemonin with heterosubstituted dienes. Synthesis of polyfunctional oxaspiro[4.5]decanes.

✍ Scribed by Daniel Alonso; Josep Font; Rosa M. Ortuño; Jean d'Angelo; André Guingant; Claudette Bois

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 402 KB
Volume: 47
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86540-6

No coin nor oath required. For personal study only.

✦ Synopsis

Cycloadditions of protoaneQwmin (1) with different kinds of heterosubstituted dienes have been tried under several reaction conditions; 1 has revealed to be a good dienophile towards electron-rich dienes giving adducts that can be easily transfoned into useful synthetic building blocks.

📜 SIMILAR VOLUMES

Stereoselective Synthesis of 4,5-Diethyl

Stereoselective Synthesis of 4,5-Diethylidene-Oxazolidinones as New Dienes in Diels-Alder Reactions

✍ Rafael Martínez; Hugo A. Jiménez-Vázquez; Alicia Reyes; Joaquín Tamariz 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 339 KB 👁 2 views

The N-substituted isomeric (4Z,5Z)-and (4E,5Z)-4,5-diethylideneoxazolidin-2-ones 5 and 6 were synthesized, the latter being favored during the one-step process from the a-diketone 1c and different isocyanates. The steric interaction between the N-substituent and the Me group attached to the exocycli

ChemInform Abstract: Stereoselective Syn

ChemInform Abstract: Stereoselective Synthesis of 4,5-Diethylidene-oxazolidinones as New Dienes in Diels—Alder Reactions.

✍ Rafael Martinez; Hugo A. Jimenez-Vazquez; Alicia Reyes; Joaquin Tamariz 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

Synthesis of pyridozine by diels-alder r

Synthesis of pyridozine by diels-alder reactions with 4-methyl-5-alkoxy oxazoles

✍ R.A. Firestone; E.E. Harris; W. Reuter 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 958 KB

Diels-Alder Reactions of Ethyl α-Bromoac

Diels-Alder Reactions of Ethyl α-Bromoacrylate with Open-chain Dienes–Synthesis of Ethyl 1,3-/ 1,4-Cyclohexadienecarboxylates

✍ Yingjie Li; Quanrui Wang; Goeke Andreas 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 70 KB

Synthesis and Diels-Alder reactions of a

Synthesis and Diels-Alder reactions of a facially dissymmetric tetracyclo-fused maleic anhydride with cyclic dienes

✍ Teh-Chang Chou; Tzong-Shing Jiang; Jenn-Tsang Hwang; Cheng-Tung Lin 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 325 KB

Absbuct :Facially dissymmetti ntakic anhydridc I is synthesized and tmkrgoes Diels-Alder cyckuukiitions with cyclic dicnes exclusively on the fke syn to its etheno-bridges.

ChemInform Abstract: Diels—Alder Reactio

ChemInform Abstract: Diels—Alder Reactions of Ethyl α-Bromoacrylate with Open-Chain Dienes — Synthesis of Ethyl 1,3-/1,4-Cyclohexadienecarboxylates.

✍ Yingjie Li; Quanrui Wang; Goeke Andreas 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

## Abstract The title reaction proceeds with high regio‐ and diastereoselectivity.