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Diels-Alder Reactions of Ethyl α-Bromoacrylate with Open-chain Dienes–Synthesis of Ethyl 1,3-/ 1,4-Cyclohexadienecarboxylates

✍ Scribed by Yingjie Li; Quanrui Wang; Goeke Andreas


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
70 KB
Volume
28
Category
Article
ISSN
0256-7660

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Reactions of gaseous acylium ions with 1
✍ Aline B. Lemos; Regina Sparrapan; Marcos N. Eberlin 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB

## Abstract A novel reaction of acylium and thioacylium ions, polar [4 + 2^+^] Diels–Alder cycloaddition with 1,3‐dienes and __O__‐heterodienes, has been systematically investigated in the gas phase (Eberlin MN, Cooks RG. __J. Am. Chem. Soc.__ 1993; 115: 9226). This polar cycloaddition, yet without