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Synthesis and Diels-Alder reactions of a facially dissymmetric tetracyclo-fused maleic anhydride with cyclic dienes

✍ Scribed by Teh-Chang Chou; Tzong-Shing Jiang; Jenn-Tsang Hwang; Cheng-Tung Lin


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
325 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis


Absbuct :Facially dissymmetti ntakic anhydridc I is synthesized and tmkrgoes Diels-Alder cyckuukiitions with cyclic dicnes exclusively on the fke syn to its etheno-bridges.


📜 SIMILAR VOLUMES


Facial Stereoselective Diels–Alder Cyclo
✍ Cheng-Tung Lin; Hsiang-Chin Hsu; Mei-Fei Wang; Teh-Chang Chou 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 187 KB

AbstractÐThe Diels±Alder cycloadditions of facially dissymmetric sesquibicyclo[2.2.2]octadiene-fused maleic anhydride 1 with exocyclic 1,3-butadienes have been studied. The reactions proceeded via syn-side (relative to the etheno-bridge in 1) attack of the diene upon 1.