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Facial Stereoselective Diels–Alder Cycloadditions of a Sesquibicyclo[2.2.2]octadiene-fused Maleic Anhydride with Exocyclic 1,3-Butadienes

✍ Scribed by Cheng-Tung Lin; Hsiang-Chin Hsu; Mei-Fei Wang; Teh-Chang Chou

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 187 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00466-x

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✦ Synopsis

AbstractÐThe Diels±Alder cycloadditions of facially dissymmetric sesquibicyclo[2.2.2]octadiene-fused maleic anhydride 1 with exocyclic 1,3-butadienes have been studied. The reactions proceeded via syn-side (relative to the etheno-bridge in 1) attack of the diene upon 1.

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