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Diels-alder polymerization of a macrocyclic metal complex with p-benzoquinone

✍ Scribed by B. Hauschel; P. Stihler; M. Hanack

Book ID
117541419
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
192 KB
Volume
84
Category
Article
ISSN
0379-6779

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Organic reactions at high pressure. The
Organic reactions at high pressure. The Diels-Alder reaction of p-benzoquinone with dienic esters
✍ William G. Dauben; William R. Baker πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 190 KB

The Diels-Alder reaction of e-benzoquinone with substituted dienoic esters affords good yields of 4a,5,8,8a-tetrahydro-1,4+aphthalenediones, free from the isomeric hydroquinone. The reactions were conducted at room temperature under 15 kbar (1.5 GPa) pressure in dichloromethane solutions.