Diels-Alder Reactions of .alpha.-Substituted Styrenes with p-Benzoquinone
✍ Scribed by Willmore, Nikolaos D.; Hoic, Diego A.; Katz, Thomas J.
- Book ID
- 118015035
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 380 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0022-3263
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The Diels-Alder reaction of e-benzoquinone with substituted dienoic esters affords good yields of 4a,5,8,8a-tetrahydro-1,4+aphthalenediones, free from the isomeric hydroquinone. The reactions were conducted at room temperature under 15 kbar (1.5 GPa) pressure in dichloromethane solutions.