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Dichloro(η5-cyclopentadienyl){[1-(4-methoxyphenyl)cyclohexyl]-η5-cyclopentadienyl}titanium(IV)

✍ Scribed by Tian, J. ;Hu, N. H. ;Shen, Q. ;Huang, B. T.


Book ID
114511775
Publisher
International Union of Crystallography
Year
1995
Tongue
English
Weight
341 KB
Volume
51
Category
Article
ISSN
0108-2701

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(η-Cyclopentadienyl)[1-4-η-(5exo-cyclope
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Reaction of cobaltocene with cyclopentadiene and air results in the formation of the title compound; its structure has been elucidated by spectroscopic and X‐ray methods.

Chloridobis(η5-cyclopentadienyl)(4-metho
✍ Burford, Richard ;Garon, Christian N. ;Fontaine, Frédéric-Georges ;Westcott, Ste 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 421 KB

In the structure of the title compound, [Zr(C~5~H~5~)~2~(C~9~H~11~O)Cl], the Zr atom is in a pseudo-tetrahedral coordination environment and is coordinated by two η^5^-cyclopentadienyl (Cp) rings, a chloride ion and a 4-methoxyphenethyl group. The 4-methoxyphenethyl ligand is disordered over two pos