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Chloridobis(η5-cyclopentadienyl)(4-methoxyphenethyl)zirconium(IV)

✍ Scribed by Burford, Richard ;Garon, Christian N. ;Fontaine, Frédéric-Georges ;Westcott, Stephen A.

Book ID
104492019
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
421 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the structure of the title compound, [Zr(C~5~H~5~)~2~(C~9~H~11~O)Cl], the Zr atom is in a pseudo-tetrahedral coordination environment and is coordinated by two η^5^-cyclopentadienyl (Cp) rings, a chloride ion and a 4-methoxyphenethyl group. The 4-methoxyphenethyl ligand is disordered over two positions; the site occupancy factors are ca 0.6 and 0.4.

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Borgehalt (titrimetrisch nach oxidativer Probenaufbereitung): 1.79% (ber. ## 1. 98%). -2: 'H-NMR: 2.22 (s), 2.35 (s), 6.82 (5). 7.10-7.70 (m); IR: 512 und 530; MS: 648 (M+, 1.0%). 529 (M\*-119, 5.1%). 333 (34%), 259 (80%). 199 (63%), 119 (100%); Borgehalt: 1.64% (ber. 1.76%). -3: 'H-NMR: 7.10-7.70