𝔖 Bobbio Scriptorium
✦   LIBER   ✦

(η-Cyclopentadienyl)[1-4-η-(5exo-cyclopentadienyl-1,3-cyclopentadien)]cobalt(I)

✍ Scribed by Helmut Bönnemann; Michael Radermacher; Carl Krüger; Hans-Jüger Kraus

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
348 KB
Volume
66
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Reaction of cobaltocene with cyclopentadiene and air results in the formation of the title compound; its structure has been elucidated by spectroscopic and X‐ray methods.

📜 SIMILAR VOLUMES

Reactions of 1,8-Diheterocyclotetradeca-
Reactions of 1,8-Diheterocyclotetradeca-4,11-diynes with (η4-Cycloocta-1,5-diene)(η5-cyclopentadienyl)cobalt
✍ Volker Wolfart; Matthias Ramming; Rolf Gleiter; Bernhard Nuber; Hans Pritzkow; F 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 276 KB 👁 1 views

The following monocyclic and bicyclic 14-membered diynes all cases we obtained an intramolecular cyclobutadiene complex stabilized with a CpCo fragment (15-26). For 3 we were treated with [CpCo(cod)]: 1-oxacyclotetradeca-4,11diyne (2), 1,8-dioxacyclotetradeca-4,11-diyne (3), cyclotetra-could isolate

(η3-Allyl)(η4-butadien)(η5-cyclopentadie
(η3-Allyl)(η4-butadien)(η5-cyclopentadienyl)-zirconium, ein System isomerer Monocyclopentadienylzirconium(II)-Verbindungen
✍ Priv.-Doz. Dr. Gerhard Erker; Klaus Berg; Prof. Dr. Carl Krüger; Prof. Dr. Gerha 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 246 KB 👁 1 views

Borgehalt (titrimetrisch nach oxidativer Probenaufbereitung): 1.79% (ber. ## 1. 98%). -2: 'H-NMR: 2.22 (s), 2.35 (s), 6.82 (5). 7.10-7.70 (m); IR: 512 und 530; MS: 648 (M+, 1.0%). 529 (M\*-119, 5.1%). 333 (34%), 259 (80%). 199 (63%), 119 (100%); Borgehalt: 1.64% (ber. 1.76%). -3: 'H-NMR: 7.10-7.70