η5-Cyclopentadienyl (η5-1,3-diborolene)cobalt — A Novel Type of Sandwich Complexes with a Pentacoordinated Carbon Atom

Syntheses and electrochemical behaviour

Syntheses and electrochemical behaviour of novel dmit or dmio (dithiolato) cobalt(iii) complexes with a η5-cyclopentadienyl or η5-pentamethylcyclopentadienyl ring

✍ Hirobumi Ushijima; Susumu Sudoh; Masatsugu Kajitani; Kunio Shimizu; Takeo Akiyam 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB

## Abstract Four novel cobalt(III) complexes with a cyclopentadienyl or pentamethylcyclopentadienyl ring and dmit or dmio ligands were synthesized, and their electrochemical behaviour was investigated. All these complexes exhibited three one‐electron transfer steps: one reduction and two oxidation