✦ LIBER ✦
Syntheses and electrochemical behaviour of novel dmit or dmio (dithiolato) cobalt(iii) complexes with a η5-cyclopentadienyl or η5-pentamethylcyclopentadienyl ring
✍ Scribed by Hirobumi Ushijima; Susumu Sudoh; Masatsugu Kajitani; Kunio Shimizu; Takeo Akiyama; Akira Sugimori
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 426 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0268-2605
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✦ Synopsis
Abstract
Four novel cobalt(III) complexes with a cyclopentadienyl or pentamethylcyclopentadienyl ring and dmit or dmio ligands were synthesized, and their electrochemical behaviour was investigated. All these complexes exhibited three one‐electron transfer steps: one reduction and two oxidation steps. In addition, a novel organosulphur compound was afforded by electrochemical oxidation of dmit cobalt complex. Thus, these complexes may have considerable synthetic potential as precursors for electron reservoirs and organosulphur compounds.