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Dichloro­octa­kis(di-2,4-chloro­benz­yl)di-μ2-methano­lato-di-μ3-oxo-tetra­tin(IV)

✍ Scribed by Li, Gang ;Yin, Handong ;Wang, Daqi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
111 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Sn 4 (C 7 H 5 Cl 2 ) 8 (CH 3 O) 2 Cl 2 O 2 ], the O atoms and the methoxy groups bridge four Sn atoms to form a tetranuclear complex which is located on an inversion centre. Each Sn atom assumes a distorted trigonal-bipyramidal geometry.

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Single-crystal X-ray study T = 100 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.032 wR factor = 0.086 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.