In the title compound, [Sn 4 (C 7 H 6 F) 8 Cl 4 O 2 ]Á2H 2 O, the Cl and O atoms bridge four Sn atoms, forming a tetranuclear complex which is located on an inversion centre. The four Sn atoms are coplanar with the bridging Cl and O atoms, and the complex shows a ladder structure. Each Sn atom assum
Di-μ2-methoxo-bis[benzyl(5-chloro-2-oxidobenzaldehyde thiosemicarbazonato)tin(IV)]
✍ Scribed by Sarma, Moumita Sen ;Ellis, Carol A. ;Moitra, Nirmalya ;Roy, Abhijit ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 503 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Sn 4 (C 7 H 5 Cl 2 ) 8 (CH 3 O) 2 Cl 2 O 2 ], the O atoms and the methoxy groups bridge four Sn atoms to form a tetranuclear complex which is located on an inversion centre. Each Sn atom assumes a distorted trigonal-bipyramidal geometry.
Single-crystal X-ray study T = 100 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.032 wR factor = 0.086 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.