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Di-μ2-chloro-dichloro­octa­kis(2-fluoro­benz­yl)di-μ3-oxo-tetra­tin(IV) dihydrate

✍ Scribed by Li, Gang ;Yin, Han-Dong ;Hong, Min ;Wang, Da-Qi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
89 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Sn 4 (C 7 H 6 F) 8 Cl 4 O 2 ]Á2H 2 O, the Cl and O atoms bridge four Sn atoms, forming a tetranuclear complex which is located on an inversion centre. The four Sn atoms are coplanar with the bridging Cl and O atoms, and the complex shows a ladder structure. Each Sn atom assumes a distorted trigonal-bipyramidal geometry.

📜 SIMILAR VOLUMES

Dichloro­octa­kis(di-2,4-chloro­benz­yl)
Dichloro­octa­kis(di-2,4-chloro­benz­yl)di-μ2-methano­lato-di-μ3-oxo-tetra­tin(IV)
✍ Li, Gang ;Yin, Handong ;Wang, Daqi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 111 KB

In the title complex, [Sn 4 (C 7 H 5 Cl 2 ) 8 (CH 3 O) 2 Cl 2 O 2 ], the O atoms and the methoxy groups bridge four Sn atoms to form a tetranuclear complex which is located on an inversion centre. Each Sn atom assumes a distorted trigonal-bipyramidal geometry.

Octa-n-butyl­bis(μ2-4-chloro-3,5-dinitro
Octa-n-butyl­bis(μ2-4-chloro-3,5-dinitro­benzoato-κ2O:O′)bis­(4-chloro-3,5-dinitro­benzoato-κO)di-μ3-oxo-tetra­tin(IV)
✍ Aziz-ur-Rehman, ;Shahzadi, Saira ;Ali, Saqib ;Helliwell, Madeleine 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 207 KB

Single-crystal X-ray study T = 100 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.032 wR factor = 0.086 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.